| 3. Round | 09/09/2012 | Pro Vercelli | - | AS Livorno | 1:2 | ||||
| 13. Round | 03/11/2012 | AS Livorno | - | AS Bari | 2:1 | ||||
| 14. Round | 10/11/2012 | Ascoli Calcio | - | AS Livorno | 1:4 | ||||
| 17. Round | 01/12/2012 | AS Livorno | - | US Grosseto FC | 4:0 |  |
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| 18. Round | 08/12/2012 | Vicenza Calcio | - | AS Livorno | 3:3 | ||||
| 19. Round | 14/12/2012 | AS Livorno | - | Ternana Calcio | 2:1 |
Italy
