| 1. Round | 04/10/1942 | US Livorno | - | AC Venezia | 2:1 | ||||
| 2. Round | 11/10/1942 | Torino FC | - | US Livorno | 1:2 | ||||
| 3. Round | 18/10/1942 | US Livorno | - | AC Liguria | 3:1 | ||||
| 4. Round | 25/10/1942 | Atalanta | - | US Livorno | 0:2 | ||||
| 5. Round | 01/11/1942 | US Livorno | - | Lazio Roma | 4:2 | ||||
| 6. Round | 08/11/1942 | Bologna FC | - | US Livorno | 1:2 | ||||
| 7. Round | 15/11/1942 | US Livorno | - | AS Bari | 1:1 | ||||
| 8. Round | 22/11/1942 | AS Ambrosiana-Inter | - | US Livorno | 0:1 | ||||
| 9. Round | 29/11/1942 | US Triestina | - | US Livorno | 1:1 | ||||
| 10. Round | 06/12/1942 | US Livorno | - | Juventus | 0:3 | ||||
| 11. Round | 13/12/1942 | Genova 1893 Circolo del Calcio | - | US Livorno | 5:2 | ||||
| 12. Round | 20/12/1942 | US Livorno | - | AS Roma | 2:0 | ||||
| 13. Round | 27/12/1942 | ACF Fiorentina | - | US Livorno | 4:3 |
Italy