| 1. Round | 28/08/2022 | Sassuolo Calcio [Women] | - | UC Sampdoria [Women] | 1:2 | ||||
| 2. Round | 12/09/2022 | Parma Calcio 1913 [Women] | - | Sassuolo Calcio [Women] | 2:1 | ||||
| 6. Round | 16/10/2022 | Sassuolo Calcio [Women] | - | AS Roma [Women] | 0:1 |  |
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| 7. Round | 23/10/2022 | Sassuolo Calcio [Women] | - | Inter [Women] | 1:1 | ||||
| 9. Round | 20/11/2022 | Sassuolo Calcio [Women] | - | Pomigliano CF [Women] | 2:1 | ||||
| 10. Round | 27/11/2022 | UC Sampdoria [Women] | - | Sassuolo Calcio [Women] | 0:2 | ||||
| 11. Round | 04/12/2022 | Sassuolo Calcio [Women] | - | Parma Calcio 1913 [Women] | 2:2 | |
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| 12. Round | 10/12/2022 | Sassuolo Calcio [Women] | - | AC Milan [Women] | 0:1 | ||||
| 13. Round | 15/01/2023 | Juventus [Women] | - | Sassuolo Calcio [Women] | 1:1 | ||||
| 14. Round | 21/01/2023 | Sassuolo Calcio [Women] | - | ACF Fiorentina [Women] | 0:1 | ||||
| 15. Round | 29/01/2023 | AS Roma [Women] | - | Sassuolo Calcio [Women] | 5:0 | ||||
| 17. Round | 12/02/2023 | Sassuolo Calcio [Women] | - | FC Como Women [Women] | 2:0 | |
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| 18. Round | 25/02/2023 | Pomigliano CF [Women] | - | Sassuolo Calcio [Women] | 0:2 |
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