| 1. Round | 26/10/1941 | Atalanta | - | US Livorno | 4:0 | ||||
| 2. Round | 02/11/1941 | US Livorno | - | AC Venezia | 1:1 | ||||
| 3. Round | 09/11/1941 | US Triestina | - | US Livorno | 5:1 | ||||
| 12. Round | 11/01/1942 | Juventus | - | US Livorno | 2:3 | ||||
| 13. Round | 18/01/1942 | US Livorno | - | Genova 1893 Circolo del Calcio | 0:0 | ||||
| 14. Round | 25/01/1942 | AS Roma | - | US Livorno | 4:0 | ||||
| 24. Round | 03/05/1942 | Modena FC | - | US Livorno | 3:0 | ||||
| 27. Round | 24/05/1942 | US Livorno | - | Juventus | 1:2 |
Italy