| Ch. League | 19/04/06 | Arsenal FC | - | Villarreal CF | 1:0 | ||||
| Ch. League | 25/04/06 | Villarreal CF | - | Arsenal FC | 0:0 | ||||
| Ch. League | 07/04/09 | Villarreal CF | - | Arsenal FC | 1:1 |  |
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| Ch. League | 15/04/09 | Arsenal FC | - | Villarreal CF | 3:0 | ||||
| Primera | 29/08/11 | FC Barcelona | - | Villarreal CF | 5:0 |  |
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| Primera | 28/01/12 | Villarreal CF | - | FC Barcelona | 0:0 | ||||
| Primera | 14/12/13 | FC Barcelona | - | Villarreal CF | 2:1 | ||||
| Primera | 27/04/14 | Villarreal CF | - | FC Barcelona | 2:3 |
Spain
