| 7. Round | 23/10/2022 | AS Roma [Women] | - | FC Como Women [Women] | 1:0 |  |
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| 9. Round | 19/11/2022 | AS Roma [Women] | - | UC Sampdoria [Women] | 2:0 | ||||
| 11. Round | 04/12/2022 | AC Milan [Women] | - | AS Roma [Women] | 0:2 | ||||
| 13. Round | 14/01/2023 | ACF Fiorentina [Women] | - | AS Roma [Women] | 1:7 | ||||
| 14. Round | 22/01/2023 | Parma Calcio 1913 [Women] | - | AS Roma [Women] | 2:3 | ||||
| 15. Round | 29/01/2023 | AS Roma [Women] | - | Sassuolo Calcio [Women] | 5:0 | ||||
| 16. Round | 04/02/2023 | FC Como Women [Women] | - | AS Roma [Women] | 0:1 | ||||
| 18. Round | 26/02/2023 | UC Sampdoria [Women] | - | AS Roma [Women] | 0:1 |
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