| 1. Round | 05/09/2021 | Real Sociedad [Women] | - | Valencia CF [Women] | 4:1 | ||||
| 2. Round | 12/09/2021 | Valencia CF [Women] | - | Sporting de Huelva [Women] | 2:2 | ||||
| 3. Round | 25/09/2021 | FC Barcelona [Women] | - | Valencia CF [Women] | 8:0 | ||||
| 4. Round | 29/09/2021 | Valencia CF [Women] | - | Athletic Club [Women] | 1:3 | ||||
| 5. Round | 03/10/2021 | Valencia CF [Women] | - | Sevilla FC [Women] | 1:2 | ||||
| 6. Round | 10/10/2021 | Levante UD [Women] | - | Valencia CF [Women] | 1:0 | ||||
| 7. Round | 16/10/2021 | Valencia CF [Women] | - | Rayo Vallecano [Women] | 1:0 | ||||
| 8. Round | 31/10/2021 | Real Madrid [Women] | - | Valencia CF [Women] | 2:1 | ||||
| 9. Round | 07/11/2021 | Valencia CF [Women] | - | Atlético Madrid [Women] | 1:1 | ||||
| 10. Round | 14/11/2021 | UDG Tenerife Sur [Women] | - | Valencia CF [Women] | 2:1 | ||||
| 13. Round | 12/12/2021 | Valencia CF [Women] | - | Madrid CFF [Women] | 1:3 | ||||
| 17. Round | 12/01/2022 | Valencia CF [Women] | - | Real Sociedad [Women] | 0:3 | ||||
| 18. Round | 16/01/2022 | Sevilla FC [Women] | - | Valencia CF [Women] | 3:1 |
Slovenia