| 9. Round | 23/10/2022 | Frosinone Calcio [Youth] | - | Empoli FC [Youth] | 1:1 | ||||
| 12. Round | 12/11/2022 | Bologna FC [Youth] | - | Empoli FC [Youth] | 0:1 | ||||
| 16. Round | 30/01/2023 | SSC Napoli [Youth] | - | Empoli FC [Youth] | 1:1 | ||||
| 17. Round | 04/02/2023 | Empoli FC [Youth] | - | Torino FC [Youth] | 3:0 |  |
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| 18. Round | 12/02/2023 | Atalanta [Youth] | - | Empoli FC [Youth] | 2:2 | |
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| 19. Round | 15/02/2023 | Empoli FC [Youth] | - | ACF Fiorentina [Youth] | 2:0 | |
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| 20. Round | 20/02/2023 | Juventus [Youth] | - | Empoli FC [Youth] | 3:0 | ||||
| 22. Round | 06/03/2023 | Empoli FC [Youth] | - | Udinese Calcio [Youth] | 1:0 | ||||
| 23. Round | 13/03/2023 | AS Roma [Youth] | - | Empoli FC [Youth] | 4:1 | ||||
| 24. Round | 19/03/2023 | Empoli FC [Youth] | - | AC Milan [Youth] | 2:1 | ||||
| 25. Round | 02/04/2023 | US Lecce [Youth] | - | Empoli FC [Youth] | 2:0 |  |
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| 27. Round | 16/04/2023 | Sampdoria [Youth] | - | Empoli FC [Youth] | 2:0 | ||||
| 30. Round | 07/05/2023 | Inter [Youth] | - | Empoli FC [Youth] | 2:0 | ||||
| 31. Round | 12/05/2023 | Empoli FC [Youth] | - | Hellas Verona [Youth] | 1:0 |
Italy