| 6. Round | 10/09/2022 | SSC Napoli | - | Spezia Calcio | 1:0 | ||||
| 11. Round | 23/10/2022 | AS Roma | - | SSC Napoli | 0:1 | ||||
| 13. Round | 05/11/2022 | Atalanta | - | SSC Napoli | 1:2 | ||||
| 24. Round | 25/02/2023 | Empoli FC | - | SSC Napoli | 0:2 | ||||
| 27. Round | 19/03/2023 | Torino FC | - | SSC Napoli | 0:4 | ||||
| 36. Round | 21/05/2023 | SSC Napoli | - | Inter | 3:1 |  |
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| 37. Round | 28/05/2023 | Bologna FC | - | SSC Napoli | 2:2 | ||||
| 38. Round | 04/06/2023 | SSC Napoli | - | Sampdoria | 2:0 |
Italy