| Group A | 07/09/2022 | SSC Napoli | - | Liverpool FC | 4:1 | ||||
| Group A | 14/09/2022 | Rangers FC | - | SSC Napoli | 0:3 | ||||
| Group A | 04/10/2022 | AFC Ajax | - | SSC Napoli | 1:6 |  |
|||
| Group A | 12/10/2022 | SSC Napoli | - | AFC Ajax | 4:2 | ||||
| Group A | 26/10/2022 | SSC Napoli | - | Rangers FC | 3:0 | ||||
| Group A | 01/11/2022 | Liverpool FC | - | SSC Napoli | 2:0 | ||||
| Round of 16 | 21/02/2023 | Eintracht Frankfurt | - | SSC Napoli | 0:2 | |
|||
| Round of 16 | 15/03/2023 | SSC Napoli | - | Eintracht Frankfurt | 3:0 | ||||
| Quarter-finals | 12/04/2023 | AC Milan | - | SSC Napoli | 1:0 |  |
|||
| Quarter-finals | 18/04/2023 | SSC Napoli | - | AC Milan | 1:1 | |
Italy
