| 2. Round | 29/08/2011 | FC Barcelona | - | Villarreal CF | 5:0 | ||||
| 3. Round | 10/09/2011 | Villarreal CF | - | Sevilla FC | 2:2 |  |
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| 4. Round | 17/09/2011 | Granada CF | - | Villarreal CF | 1:0 | ||||
| 5. Round | 20/09/2011 | Villarreal CF | - | RCD Mallorca | 2:0 | |
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| 6. Round | 24/09/2011 | Athletic Club | - | Villarreal CF | 1:1 | ||||
| 7. Round | 01/10/2011 | Villarreal CF | - | Real Zaragoza | 2:2 | |
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| 8. Round | 15/10/2011 | Getafe CF | - | Villarreal CF | 0:0 | |
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| 9. Round | 23/10/2011 | Villarreal CF | - | Levante UD | 0:3 | |
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| 10. Round | 26/10/2011 | Real Madrid | - | Villarreal CF | 3:0 |
USA
