| 3. Round | 17/09/2005 | RCD Mallorca | - | Real Sociedad | 5:2 |  |
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| 4. Round | 21/09/2005 | Getafe CF | - | RCD Mallorca | 1:1 | ||||
| 5. Round | 25/09/2005 | RCD Mallorca | - | Málaga CF | 1:4 | |
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| 6. Round | 02/10/2005 | Real Madrid | - | RCD Mallorca | 4:0 | ||||
| 7. Round | 16/10/2005 | RCD Mallorca | - | Racing Santander | 0:0 | ||||
| 11. Round | 26/10/2005 | RCD Mallorca | - | RC Celta | 1:0 | ||||
| 13. Round | 26/11/2005 | RCD Mallorca | - | Athletic Club | 0:1 | ||||
| 15. Round | 11/12/2005 | CA Osasuna | - | RCD Mallorca | 1:0 | ||||
| 16. Round | 18/12/2005 | RCD Mallorca | - | Atlético Madrid | 2:2 |
Greece