| 4. Round | 29/08/2021 | Stade de Reims | - | Paris Saint-Germain | 0:2 |  |
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| 8. Round | 25/09/2021 | Paris Saint-Germain | - | Montpellier HSC | 2:0 | ||||
| 14. Round | 20/11/2021 | Paris Saint-Germain | - | FC Nantes | 3:1 | ||||
| 15. Round | 28/11/2021 | AS Saint-Étienne | - | Paris Saint-Germain | 1:3 | ||||
| 16. Round | 01/12/2021 | Paris Saint-Germain | - | OGC Nice | 0:0 | ||||
| 17. Round | 04/12/2021 | RC Lens | - | Paris Saint-Germain | 1:1 | ||||
| 20. Round | 09/01/2022 | Olympique Lyonnais | - | Paris Saint-Germain | 1:1 | ||||
| 21. Round | 15/01/2022 | Paris Saint-Germain | - | Stade Brestois 29 | 2:0 | ||||
| 22. Round | 23/01/2022 | Paris Saint-Germain | - | Stade de Reims | 4:0 | ||||
| 23. Round | 06/02/2022 | Lille OSC | - | Paris Saint-Germain | 1:5 | |
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| 24. Round | 11/02/2022 | Paris Saint-Germain | - | Stade Rennais | 1:0 | ||||
| 28. Round | 13/03/2022 | Paris Saint-Germain | - | Girondins Bordeaux | 3:0 |  |
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| 29. Round | 20/03/2022 | AS Monaco | - | Paris Saint-Germain | 3:0 | ||||
| 30. Round | 03/04/2022 | Paris Saint-Germain | - | FC Lorient | 5:1 |
Argentina
