| 1. Round | 19/09/2020 | Sassuolo Calcio [Youth] | - | Empoli FC [Youth] | 3:2 | ||||
| 2. Round | 25/09/2020 | Empoli FC [Youth] | - | Juventus [Youth] | 0:2 | ||||
| 3. Round | 04/10/2020 | Atalanta [Youth] | - | Empoli FC [Youth] | 2:4 |  |
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| 7. Round | 22/01/2021 | Empoli FC [Youth] | - | Bologna FC [Youth] | 0:2 | ||||
| 4. Round | 26/01/2021 | Sampdoria [Youth] | - | Empoli FC [Youth] | 4:1 | ||||
| 8. Round | 31/01/2021 | Empoli FC [Youth] | - | Genoa CFC [Youth] | 5:1 | ||||
| 5. Round | 07/02/2021 | Empoli FC [Youth] | - | ACF Fiorentina [Youth] | 3:1 | ||||
| 10. Round | 18/02/2021 | Empoli FC [Youth] | - | Ascoli Calcio [Youth] | 2:1 | ||||
| 13. Round | 28/04/2021 | Torino FC [Youth] | - | Empoli FC [Youth] | 0:4 | ||||
| 21. Round | 02/05/2021 | Empoli FC [Youth] | - | AC Milan [Youth] | 1:1 | ||||
| 22. Round | 08/05/2021 | Bologna FC [Youth] | - | Empoli FC [Youth] | 1:4 | ||||
| 18. Round | 12/05/2021 | Empoli FC [Youth] | - | Atalanta [Youth] | 1:2 | ||||
| 25. Round | 26/05/2021 | Ascoli Calcio [Youth] | - | Empoli FC [Youth] | 1:3 | ||||
| 28. Round | 09/06/2021 | Empoli FC [Youth] | - | Torino FC [Youth] | 0:2 | ||||
| 29. Round | 12/06/2021 | Cagliari Calcio [Youth] | - | Empoli FC [Youth] | 5:1 |
Italy