| 1. Round | 25/08/2012 | Juve Stabia | - | AS Livorno | 1:3 | ||||
| 2. Round | 03/09/2012 | AS Livorno | - | Calcio Padova | 3:2 | ||||
| 3. Round | 09/09/2012 | Pro Vercelli | - | AS Livorno | 1:2 | ||||
| 4. Round | 15/09/2012 | AS Livorno | - | Empoli FC | 4:2 | ||||
| 5. Round | 22/09/2012 | Modena FC | - | AS Livorno | 1:0 | ||||
| 6. Round | 25/09/2012 | AS Livorno | - | AS Cittadella | 2:2 | ||||
| 7. Round | 29/09/2012 | FC Crotone | - | AS Livorno | 1:2 | ||||
| 8. Round | 08/10/2012 | AS Livorno | - | Spezia Calcio | 1:5 |  |
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| 25. Round | 11/02/2013 | Empoli FC | - | AS Livorno | 2:1 | ||||
| 26. Round | 16/02/2013 | AS Livorno | - | Modena FC | 1:2 | ||||
| 27. Round | 23/02/2013 | AS Cittadella | - | AS Livorno | 0:2 | ||||
| 28. Round | 26/02/2013 | AS Livorno | - | FC Crotone | 1:2 | ||||
| 29. Round | 02/03/2013 | Spezia Calcio | - | AS Livorno | 1:2 |  |
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| 35. Round | 06/04/2013 | AS Livorno | - | Ascoli Calcio | 3:0 | ||||
| 36. Round | 13/04/2013 | AS Varese 1910 | - | AS Livorno | 1:3 | ||||
| 37. Round | 17/04/2013 | AS Livorno | - | Novara Calcio | 1:3 | ||||
| 42. Round | 18/05/2013 | Sassuolo Calcio | - | AS Livorno | 1:0 |
Italy
