| 1. Round | 14/09/2019 | ASD Pink Bari [Women] | - | Sassuolo Calcio [Women] | 3:3 |  |
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| 2. Round | 21/09/2019 | Sassuolo Calcio [Women] | - | Juventus [Women] | 1:3 | ||||
| 3. Round | 12/10/2019 | Orobica Calcio Bergamo [Women] | - | Sassuolo Calcio [Women] | 0:1 | ||||
| 4. Round | 19/10/2019 | Sassuolo Calcio [Women] | - | ACF Fiorentina [Women] | 1:2 | |
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| 5. Round | 03/11/2019 | AS Roma [Women] | - | Sassuolo Calcio [Women] | 2:1 | ||||
| 6. Round | 16/11/2019 | Sassuolo Calcio [Women] | - | UPC Tavagnacco [Women] | 2:0 | |
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| 7. Round | 23/11/2019 | AC Milan [Women] | - | Sassuolo Calcio [Women] | 1:0 |
Italy