| 2. Round | 06/10/1968 | Inter | - | SSC Napoli | 1:1 | ||||
| 3. Round | 13/10/1968 | SSC Napoli | - | Sampdoria | 0:3 |  |
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| 4. Round | 27/10/1968 | SSC Napoli | - | AS Roma | 0:0 | ||||
| 5. Round | 03/11/1968 | Torino FC | - | SSC Napoli | 0:0 | ||||
| 6. Round | 10/11/1968 | Bologna FC | - | SSC Napoli | 2:1 | ||||
| 7. Round | 17/11/1968 | SSC Napoli | - | SSC Palermo | 1:0 | ||||
| 8. Round | 24/11/1968 | SS L.R. Vicenza | - | SSC Napoli | 2:0 | ||||
| 9. Round | 01/12/1968 | SSC Napoli | - | Juventus | 2:1 | ||||
| 10. Round | 08/12/1968 | ACF Fiorentina | - | SSC Napoli | 2:1 |  |
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| 11. Round | 15/12/1968 | SSC Napoli | - | AS Varese 1910 | 1:1 | ||||
| 12. Round | 22/12/1968 | SSC Napoli | - | Atalanta | 2:0 | ||||
| 13. Round | 12/01/1969 | Cagliari Calcio | - | SSC Napoli | 0:0 | |
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| 14. Round | 19/01/1969 | SSC Napoli | - | AC Milan | 0:0 | ||||
| 15. Round | 26/01/1969 | Pisa SC | - | SSC Napoli | 1:0 | ||||
| 17. Round | 09/02/1969 | SSC Napoli | - | Inter | 3:1 | ||||
| 18. Round | 16/02/1969 | Sampdoria | - | SSC Napoli | 0:2 | ||||
| 19. Round | 23/02/1969 | AS Roma | - | SSC Napoli | 0:0 | ||||
| 28. Round | 04/05/1969 | SSC Napoli | - | Cagliari Calcio | 2:1 | |
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| 29. Round | 11/05/1969 | AC Milan | - | SSC Napoli | 0:0 | ||||
| 30. Round | 18/05/1969 | SSC Napoli | - | Pisa SC | 2:1 |
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