| 1. Round | 29/09/1968 | SSC Napoli | - | Hellas Verona | 1:1 | ||||
| 2. Round | 06/10/1968 | Inter | - | SSC Napoli | 1:1 | ||||
| 3. Round | 13/10/1968 | SSC Napoli | - | Sampdoria | 0:3 | ||||
| 8. Round | 24/11/1968 | SS L.R. Vicenza | - | SSC Napoli | 2:0 | ||||
| 15. Round | 26/01/1969 | Pisa SC | - | SSC Napoli | 1:0 | ||||
| 16. Round | 02/02/1969 | Hellas Verona | - | SSC Napoli | 1:0 | ||||
| 17. Round | 09/02/1969 | SSC Napoli | - | Inter | 3:1 | ||||
| 18. Round | 16/02/1969 | Sampdoria | - | SSC Napoli | 0:2 |  |
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| 19. Round | 23/02/1969 | AS Roma | - | SSC Napoli | 0:0 | ||||
| 20. Round | 02/03/1969 | SSC Napoli | - | Torino FC | 0:0 | ||||
| 21. Round | 09/03/1969 | SSC Napoli | - | Bologna FC | 1:1 | ||||
| 22. Round | 16/03/1969 | SSC Palermo | - | SSC Napoli | 0:2 dec. | ||||
| 23. Round | 23/03/1969 | SSC Napoli | - | SS L.R. Vicenza | 1:0 | ||||
| 24. Round | 06/04/1969 | Juventus | - | SSC Napoli | 2:0 | ||||
| 25. Round | 13/04/1969 | SSC Napoli | - | ACF Fiorentina | 1:3 | ||||
| 26. Round | 20/04/1969 | AS Varese 1910 | - | SSC Napoli | 1:2 | |
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| 27. Round | 27/04/1969 | Atalanta | - | SSC Napoli | 0:0 | ||||
| 28. Round | 04/05/1969 | SSC Napoli | - | Cagliari Calcio | 2:1 | ||||
| 29. Round | 11/05/1969 | AC Milan | - | SSC Napoli | 0:0 | ||||
| 30. Round | 18/05/1969 | SSC Napoli | - | Pisa SC | 2:1 |
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