| Group A | 14/09/2011 | Manchester City | - | SSC Napoli | 1:1 |  |
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| Group A | 27/09/2011 | SSC Napoli | - | Villarreal CF | 2:0 | |
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| Group A | 18/10/2011 | SSC Napoli | - | Bayern München | 1:1 | |
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| Group A | 22/11/2011 | SSC Napoli | - | Manchester City | 2:1 | ||||
| Group A | 07/12/2011 | Villarreal CF | - | SSC Napoli | 0:2 | ||||
| Round of 16 | 21/02/2012 | SSC Napoli | - | Chelsea FC | 3:1 | ||||
| Round of 16 | 14/03/2012 | Chelsea FC | - | SSC Napoli | 4:1 aet | |
Italy