| 2. Round | 12/09/2022 | Parma Calcio 1913 [Women] | - | Sassuolo Calcio [Women] | 2:1 |  |
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| 4. Round | 24/09/2022 | Sassuolo Calcio [Women] | - | Juventus [Women] | 1:1 | |
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| 5. Round | 01/10/2022 | ACF Fiorentina [Women] | - | Sassuolo Calcio [Women] | 2:0 | ||||
| 6. Round | 16/10/2022 | Sassuolo Calcio [Women] | - | AS Roma [Women] | 0:1 | ||||
| 9. Round | 20/11/2022 | Sassuolo Calcio [Women] | - | Pomigliano CF [Women] | 2:1 | |
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| 10. Round | 27/11/2022 | UC Sampdoria [Women] | - | Sassuolo Calcio [Women] | 0:2 | ||||
| 11. Round | 04/12/2022 | Sassuolo Calcio [Women] | - | Parma Calcio 1913 [Women] | 2:2 | ||||
| 15. Round | 29/01/2023 | AS Roma [Women] | - | Sassuolo Calcio [Women] | 5:0 | ||||
| 16. Round | 05/02/2023 | Inter [Women] | - | Sassuolo Calcio [Women] | 3:0 | ||||
| 18. Round | 25/02/2023 | Pomigliano CF [Women] | - | Sassuolo Calcio [Women] | 0:2 |
Italy