| 3. Round | 27/09/2020 | FC Barcelona | - | Villarreal CF | 4:0 | ||||
| 4. Round | 01/10/2020 | RC Celta | - | FC Barcelona | 0:3 |  |
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| 5. Round | 04/10/2020 | FC Barcelona | - | Sevilla FC | 1:1 | ||||
| 6. Round | 17/10/2020 | Getafe CF | - | FC Barcelona | 1:0 |  |
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| 8. Round | 31/10/2020 | CD Alavés | - | FC Barcelona | 1:1 | ||||
| 9. Round | 07/11/2020 | FC Barcelona | - | Real Betis | 5:2 | ||||
| 10. Round | 21/11/2020 | Atlético Madrid | - | FC Barcelona | 1:0 | ||||
| 21. Round | 31/01/2021 | FC Barcelona | - | Athletic Club | 2:1 | ||||
| 30. Round | 10/04/2021 | Real Madrid | - | FC Barcelona | 2:1 | ||||
| 31. Round | 22/04/2021 | FC Barcelona | - | Getafe CF | 5:2 | ||||
| 32. Round | 25/04/2021 | Villarreal CF | - | FC Barcelona | 1:2 | ||||
| 33. Round | 29/04/2021 | FC Barcelona | - | Granada CF | 1:2 | ||||
| 34. Round | 02/05/2021 | Valencia CF | - | FC Barcelona | 2:3 | ||||
| 35. Round | 08/05/2021 | FC Barcelona | - | Atlético Madrid | 0:0 | ||||
| 36. Round | 11/05/2021 | Levante UD | - | FC Barcelona | 3:3 |
Spain
