| 17. Round | 04/02/2023 | Inter [Youth] | - | SSC Napoli [Youth] | 4:0 | ||||
| 19. Round | 14/02/2023 | Cesena FC [Youth] | - | SSC Napoli [Youth] | 0:2 |  |
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| 22. Round | 04/03/2023 | AS Roma [Youth] | - | SSC Napoli [Youth] | 4:0 | ||||
| 23. Round | 11/03/2023 | SSC Napoli [Youth] | - | Cagliari Calcio [Youth] | 1:0 | ||||
| 24. Round | 19/03/2023 | Bologna FC [Youth] | - | SSC Napoli [Youth] | 0:1 | ||||
| 25. Round | 02/04/2023 | SSC Napoli [Youth] | - | Torino FC [Youth] | 0:1 | ||||
| 26. Round | 08/04/2023 | Atalanta [Youth] | - | SSC Napoli [Youth] | 0:0 | ||||
| 27. Round | 16/04/2023 | Udinese Calcio [Youth] | - | SSC Napoli [Youth] | 0:2 | ||||
| 28. Round | 22/04/2023 | SSC Napoli [Youth] | - | Hellas Verona [Youth] | 1:3 | ||||
| 29. Round | 30/04/2023 | Sampdoria [Youth] | - | SSC Napoli [Youth] | 3:1 | ||||
| 30. Round | 07/05/2023 | SSC Napoli [Youth] | - | AC Milan [Youth] | 1:1 | ||||
| 31. Round | 13/05/2023 | Juventus [Youth] | - | SSC Napoli [Youth] | 2:1 | ||||
| 32. Round | 17/05/2023 | SSC Napoli [Youth] | - | ACF Fiorentina [Youth] | 0:1 |
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