| 1. Round | 15/09/2019 | Florentia San Gimignano [Women] | - | ACF Fiorentina [Women] | 2:4 | ||||
| 2. Round | 22/09/2019 | ACF Fiorentina [Women] | - | AS Roma [Women] | 0:2 |  |
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| 4. Round | 19/10/2019 | Sassuolo Calcio [Women] | - | ACF Fiorentina [Women] | 1:2 |  |
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| 5. Round | 02/11/2019 | ACF Fiorentina [Women] | - | AC Milan [Women] | 1:1 | ||||
| 13. Round | 26/01/2020 | AS Roma [Women] | - | ACF Fiorentina [Women] | 2:2 |  |
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| 14. Round | 01/02/2020 | UPC Tavagnacco [Women] | - | ACF Fiorentina [Women] | 0:1 | ||||
| 15. Round | 15/02/2020 | ACF Fiorentina [Women] | - | Sassuolo Calcio [Women] | 2:1 |
Germany