| 2. Round | 11/09/2022 | ACF Fiorentina [Women] | - | FC Como Women [Women] | 2:1 | ||||
| 3. Round | 18/09/2022 | ACF Fiorentina [Women] | - | Parma Calcio 1913 [Women] | 2:1 | ||||
| 4. Round | 24/09/2022 | AS Roma [Women] | - | ACF Fiorentina [Women] | 2:1 | ||||
| 5. Round | 01/10/2022 | ACF Fiorentina [Women] | - | Sassuolo Calcio [Women] | 2:0 | ||||
| 6. Round | 15/10/2022 | Pomigliano CF [Women] | - | ACF Fiorentina [Women] | 0:1 | ||||
| 7. Round | 23/10/2022 | ACF Fiorentina [Women] | - | UC Sampdoria [Women] | 2:1 | ||||
| 9. Round | 20/11/2022 | ACF Fiorentina [Women] | - | Inter [Women] | 0:0 | ||||
| 10. Round | 26/11/2022 | ACF Fiorentina [Women] | - | AC Milan [Women] | 1:6 |  |
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| 11. Round | 04/12/2022 | FC Como Women [Women] | - | ACF Fiorentina [Women] | 2:3 | ||||
| 12. Round | 10/12/2022 | Parma Calcio 1913 [Women] | - | ACF Fiorentina [Women] | 0:4 | ||||
| 13. Round | 14/01/2023 | ACF Fiorentina [Women] | - | AS Roma [Women] | 1:7 | ||||
| 14. Round | 21/01/2023 | Sassuolo Calcio [Women] | - | ACF Fiorentina [Women] | 0:1 | ||||
| 15. Round | 28/01/2023 | ACF Fiorentina [Women] | - | Pomigliano CF [Women] | 2:0 | ||||
| 16. Round | 04/02/2023 | UC Sampdoria [Women] | - | ACF Fiorentina [Women] | 1:4 |
Germany