| 4. Round | 25/10/2006 | CF Badalona | - | FC Barcelona | 1:2 | ||||
| 4. Round | 08/11/2006 | FC Barcelona | - | CF Badalona | 4:0 | ||||
| Round of 16 | 10/01/2007 | CD Alavés | - | FC Barcelona | 0:2 | ||||
| Round of 16 | 16/01/2007 | FC Barcelona | - | CD Alavés | 3:2 |
| 4. Round | 25/10/2006 | CF Badalona | - | FC Barcelona | 1:2 | ||||
| 4. Round | 08/11/2006 | FC Barcelona | - | CF Badalona | 4:0 | ||||
| Round of 16 | 10/01/2007 | CD Alavés | - | FC Barcelona | 0:2 | ||||
| Round of 16 | 16/01/2007 | FC Barcelona | - | CD Alavés | 3:2 |
| Thiago Motta Santon Olivares | |
| Born: | 28.08.1982 |
| Place of birth: |
São Bernardo do Campo, 
Brazil |
| Nationality: |
Italy
Brazil |
| Height: | 187 cm |
| Weight: | 83 kg |
| Position(s): | Defensive Midfielder Central Midfielder |
| Foot: | left |
