| 3. Round | 26/08/2012 | Paris Saint-Germain | - | Girondins Bordeaux | 0:0 | ||||
| 4. Round | 02/09/2012 | Lille OSC | - | Paris Saint-Germain | 1:2 |  |
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| 5. Round | 14/09/2012 | Paris Saint-Germain | - | Toulouse FC | 2:0 | ||||
| 12. Round | 11/11/2012 | Montpellier HSC | - | Paris Saint-Germain | 1:1 | |
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| 16. Round | 08/12/2012 | Paris Saint-Germain | - | Évian Thonon Gaillard | 4:0 |  |
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| 17. Round | 11/12/2012 | Valenciennes FC | - | Paris Saint-Germain | 0:4 | ||||
| 18. Round | 16/12/2012 | Paris Saint-Germain | - | Olympique Lyonnais | 1:0 | ||||
| 19. Round | 21/12/2012 | Stade Brestois 29 | - | Paris Saint-Germain | 0:3 | ||||
| 20. Round | 11/01/2013 | Paris Saint-Germain | - | AC Ajaccio | 0:0 |  |
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| 22. Round | 27/01/2013 | Paris Saint-Germain | - | Lille OSC | 1:0 | |
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| 32. Round | 13/04/2013 | ESTAC Troyes | - | Paris Saint-Germain | 0:1 | ||||
| 36. Round | 12/05/2013 | Olympique Lyonnais | - | Paris Saint-Germain | 0:1 | |
Brazil
