| 1. Round | 15/08/2022 | Getafe CF | - | Atlético Madrid | 0:3 | ||||
| 2. Round | 21/08/2022 | Atlético Madrid | - | Villarreal CF | 0:2 |  |
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| 3. Round | 29/08/2022 | Valencia CF | - | Atlético Madrid | 0:1 | |
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| 4. Round | 03/09/2022 | Real Sociedad | - | Atlético Madrid | 1:1 | ||||
| 5. Round | 10/09/2022 | Atlético Madrid | - | RC Celta | 4:1 | ||||
| 6. Round | 18/09/2022 | Atlético Madrid | - | Real Madrid | 1:2 | ||||
| 7. Round | 01/10/2022 | Sevilla FC | - | Atlético Madrid | 0:2 | |
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| 8. Round | 08/10/2022 | Atlético Madrid | - | Girona FC | 2:1 | ||||
| 9. Round | 15/10/2022 | Athletic Club | - | Atlético Madrid | 0:1 | ||||
| 11. Round | 23/10/2022 | Real Betis | - | Atlético Madrid | 1:2 | ||||
| 12. Round | 29/10/2022 | Cádiz CF | - | Atlético Madrid | 3:2 |  |
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| 13. Round | 06/11/2022 | Atlético Madrid | - | Espanyol Barcelona | 1:1 | |
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| 15. Round | 29/12/2022 | Atlético Madrid | - | Elche CF | 2:0 | |
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| 16. Round | 08/01/2023 | Atlético Madrid | - | FC Barcelona | 0:1 |
Portugal
