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| 1st(1st leg) | Empoli FC | - | Inter | 0:2 (0:0) | ||
| 2nd (2nd leg) | Inter | - | Empoli FC | 2:0 (1:0) | ||
| 1st(1st leg): 09/01/2007 20:00 | 2nd (2nd leg): 17/01/2007 20:00 | Winner: Inter | ||||
| 1st(1st leg) | Sampdoria | - | Chievo Verona | 1:0 (1:0) | ||
| 2nd (2nd leg) | Chievo Verona | - | Sampdoria | 1:2 (1:1) | ||
| 1st(1st leg): 10/01/2007 19:30 | 2nd (2nd leg): 17/01/2007 14:00 | Winner: Sampdoria | ||||
| 1st(1st leg) | AS Roma | - | Parma FC | 2:1 (1:0) | ||
| 2nd (2nd leg) | Parma FC | - | AS Roma | 2:2 (2:1) | ||
| 1st(1st leg): 10/01/2007 20:00 | 2nd (2nd leg): 17/01/2007 16:30 | Winner: AS Roma | ||||
| 1st(1st leg) | AC Milan | - | AC Arezzo | 2:0 (1:0) | ||
| 2nd (2nd leg) | AC Arezzo | - | AC Milan | 1:0 (0:0) | ||
| 1st(1st leg): 11/01/2007 20:00 | 2nd (2nd leg): 18/01/2007 20:00 | Winner: AC Milan | ||||
