| 17. Round | 17/12/2005 | 1. FSV Mainz 05 | - | MSV Duisburg | 1:1 |  |
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| 18. Round | 28/01/2006 | VfB Stuttgart | - | MSV Duisburg | 0:1 | ||||
| 23. Round | 26/02/2006 | MSV Duisburg | - | Hertha BSC | 2:1 | |
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| 24. Round | 04/03/2006 | 1. FC Nürnberg | - | MSV Duisburg | 3:0 | ||||
| 25. Round | 11/03/2006 | MSV Duisburg | - | Hannover 96 | 0:0 | |
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| 26. Round | 18/03/2006 | Eintracht Frankfurt | - | MSV Duisburg | 5:2 |  |
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| 27. Round | 25/03/2006 | MSV Duisburg | - | Bayern München | 1:3 | ||||
| 31. Round | 22/04/2006 | 1. FC Köln | - | MSV Duisburg | 3:1 | ||||
| 32. Round | 03/05/2006 | MSV Duisburg | - | Werder Bremen | 3:5 | |
Poland