| 7. Round | 06/11/2022 | Eintracht Frankfurt [Women] | - | 1. FC Köln [Women] | 2:0 | ||||
| 8. Round | 27/11/2022 | 1. FC Köln [Women] | - | VfL Wolfsburg [Women] | 0:4 | ||||
| 9. Round | 04/12/2022 | SV Meppen [Women] | - | 1. FC Köln [Women] | 1:0 | ||||
| 10. Round | 11/12/2022 | 1. FC Köln [Women] | - | SC Freiburg [Women] | 0:0 | ||||
| 11. Round | 03/02/2023 | SGS Essen [Women] | - | 1. FC Köln [Women] | 4:0 | ||||
| 12. Round | 12/02/2023 | 1899 Hoffenheim [Women] | - | 1. FC Köln [Women] | 4:0 | ||||
| 13. Round | 05/03/2023 | 1. FC Köln [Women] | - | Bayer Leverkusen [Women] | 0:0 |
Poland