| #1 | 04/10/1959 | Switzerland | - | Germany | 0:4 |  |
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| #2 | 21/10/1959 | Germany | - | Netherlands | 7:0 | |
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| #3 | 08/11/1959 | Hungary | - | Germany | 4:3 | |
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| #4 | 20/12/1959 | Germany | - | Yugoslavia | 1:1 | ||||
| #5 | 23/03/1960 | Germany | - | Chile | 2:1 | ||||
| #6 | 27/04/1960 | Germany | - | Portugal | 2:1 | ||||
| #7 | 11/05/1960 | Germany | - | Ireland | 0:1 | ||||
| #8 | 03/08/1960 | Iceland | - | Germany | 0:5 | ||||
| #9 | 26/10/1960 | Northern Ireland | - | Germany | 3:4 | |
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| #10 | 20/11/1960 | Greece | - | Germany | 0:3 | |
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| #11 | 23/11/1960 | Bulgaria | - | Germany | 2:1 | ||||
| #12 | 08/03/1961 | Germany | - | Belgium | 1:0 | ||||
| #13 | 26/03/1961 | Chile | - | Germany | 3:1 | ||||
| #14 | 10/05/1961 | Germany | - | Northern Ireland | 2:1 | |
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| #15 | 20/09/1961 | Germany | - | Denmark | 5:1 | |
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| #16 | 08/10/1961 | Poland | - | Germany | 0:2 | |
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| #17 | 22/10/1961 | Germany | - | Greece | 2:1 | ||||
| #18 | 11/04/1962 | Germany | - | Uruguay | 3:0 | ||||
| #19 | 31/05/1962 | Germany | - | Italy | 0:0 | ||||
| #20 | 03/06/1962 | Germany | - | Switzerland | 2:1 | |
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| #21 | 06/06/1962 | Germany | - | Chile | 2:0 | ||||
| #22 | 10/06/1962 | Yugoslavia | - | Germany | 1:0 | ||||
| #23 | 23/03/1966 | Netherlands | - | Germany | 2:4 | ||||
| #24 | 12/07/1966 | Germany | - | Switzerland | 5:0 | ||||
| #25 | 16/07/1966 | Germany | - | Argentina | 0:0 |
Germany