| 4. Round | 19/11/2021 | SL Benfica | - | Paços de Ferreira | 4:1 |  |
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| Round of 16 | 23/12/2021 | FC Porto | - | SL Benfica | 3:0 |
| 4. Round | 19/11/2021 | SL Benfica | - | Paços de Ferreira | 4:1 | |
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| Round of 16 | 23/12/2021 | FC Porto | - | SL Benfica | 3:0 |
| Alejandro Grimaldo García | |
| Born: | 20.09.1995 |
| Place of birth: |
Valencia, 
Spain |
| Nationality: |
Spain
|
| Height: | 171 cm |
| Weight: | 69 kg |
| Position(s): | Left Back Left Midfielder |
| Foot: | left |
