| 3. Round | 15/10/2022 | Caldas SC | - | SL Benfica | 3:5 pso |  |
|||
| 4. Round | 09/11/2022 | GD Estoril | - | SL Benfica | 0:1 | ||||
| Round of 16 | 10/01/2023 | Varzim SC | - | SL Benfica | 0:2 |  |
|||
| Quarter-finals | 09/02/2023 | Sporting Braga | - | SL Benfica | 5:4 pso |
| 3. Round | 15/10/2022 | Caldas SC | - | SL Benfica | 3:5 pso | |
|||
| 4. Round | 09/11/2022 | GD Estoril | - | SL Benfica | 0:1 | ||||
| Round of 16 | 10/01/2023 | Varzim SC | - | SL Benfica | 0:2 | |
|||
| Quarter-finals | 09/02/2023 | Sporting Braga | - | SL Benfica | 5:4 pso |
| Alejandro Grimaldo García | |
| Born: | 20.09.1995 |
| Place of birth: |
Valencia, 
Spain |
| Nationality: |
Spain
|
| Height: | 171 cm |
| Weight: | 69 kg |
| Position(s): | Left Back Left Midfielder |
| Foot: | left |
