| 1. Round | 21/08/1981 | Dynamo Fürstenwalde | - | 1. FC Union Berlin | 1:1 | ||||
| 2. Round | 28/08/1981 | 1. FC Union Berlin | - | BSG Chemie PCK Schwedt | 2:0 | ||||
| 4. Round | 19/09/1981 | 1. FC Union Berlin | - | Motor Hennigsdorf | 0:0 | ||||
| 6. Round | 07/10/1981 | 1. FC Union Berlin | - | BSG Stahl Finow | 3:1 |  |
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| 7. Round | 11/10/1981 | KWO Berlin | - | 1. FC Union Berlin | 1:1 | ||||
| 8. Round | 24/10/1981 | 1. FC Union Berlin | - | Stahl Eisenhüttenstadt | 1:1 | ||||
| 9. Round | 30/10/1981 | BSG Stahl Brandenburg | - | 1. FC Union Berlin | 3:0 | ||||
| 10. Round | 06/11/1981 | 1. FC Union Berlin | - | BSG Stahl Hennigsdorf | 4:2 | ||||
| 11. Round | 13/11/1981 | BSG Bergmann Borsig | - | 1. FC Union Berlin | 1:4 | ||||
| 12. Round | 28/11/1981 | 1. FC Union Berlin | - | Dynamo Fürstenwalde | 4:0 | ||||
| 14. Round | 12/12/1981 | 1. FC Union Berlin | - | BSG Motor Babelsberg | 1:0 | ||||
| 16. Round | 04/03/1982 | 1. FC Union Berlin | - | BSG EAB 47 Berlin | 5:2 |
Germany