| 1. Round | 27/08/2000 | TSV 1896 Rain | - | FC Schalke 04 | 0:7 |  |
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| 2. Round | 01/11/2000 | FC St. Pauli | - | FC Schalke 04 | 1:3 aet | ||||
| Round of 16 | 29/11/2000 | FC Schalke 04 | - | Borussia Dortmund | 2:1 | ||||
| Quarter-finals | 20/12/2000 | 1. FC Magdeburg | - | FC Schalke 04 | 0:1 |  |
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| Semi-finals | 07/02/2001 | VfB Stuttgart | - | FC Schalke 04 | 0:3 | ||||
| Final | 26/05/2001 | 1. FC Union Berlin | - | FC Schalke 04 | 0:2 |
Germany