| 15. Round | 09/02/2014 | 1. FC Union Berlin [Youth B] | - | VfL Osnabrück [Youth B] | 2:0 | ||||
| 22. Round | 04/05/2014 | FC St. Pauli [Youth B] | - | 1. FC Union Berlin [Youth B] | 2:1 | ||||
| 20. Round | 10/05/2014 | RB Leipzig [Youth B] | - | 1. FC Union Berlin [Youth B] | 3:1 |  |
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| 16. Round | 17/05/2014 | Holstein Kiel [Youth B] | - | 1. FC Union Berlin [Youth B] | 3:2 | ||||
| 23. Round | 24/05/2014 | 1. FC Union Berlin [Youth B] | - | Werder Bremen [Youth B] | 3:1 | ||||
| 26. Round | 15/06/2014 | 1. FC Union Berlin [Youth B] | - | VfL Wolfsburg [Youth B] | 0:3 |
Germany