| 1. Round | 28/08/1971 | FC Karl-Marx-Stadt | - | 1. FC Union Berlin | 1:1 | ||||
| 7. Round | 05/11/1971 | 1. FC Union Berlin | - | Hansa Rostock | 1:1 | ||||
| 16. Round | 21/01/1972 | 1. FC Union Berlin | - | BSG Wismut Aue | 0:0 | ||||
| 19. Round | 10/03/1972 | 1. FC Union Berlin | - | FC Vorwärts Frankfurt/Oder | 0:1 | ||||
| 20. Round | 17/03/1972 | Hansa Rostock | - | 1. FC Union Berlin | 0:1 | ||||
| 21. Round | 25/03/1972 | 1. FC Union Berlin | - | BSG Sachsenring Zwickau | 0:0 | ||||
| 22. Round | 01/04/1972 | 1. FC Magdeburg | - | 1. FC Union Berlin | 1:0 | ||||
| 23. Round | 15/04/1972 | 1. FC Union Berlin | - | 1. FC Lokomotive Leipzig | 4:1 | ||||
| 24. Round | 06/05/1972 | Dynamo Dresden | - | 1. FC Union Berlin | 4:1 | ||||
| 25. Round | 17/05/1972 | 1. FC Union Berlin | - | BFC Dynamo | 0:0 | ||||
| 26. Round | 21/05/1972 | HFC Chemie | - | 1. FC Union Berlin | 5:1 |
Germany