| 1. Round | 02/09/2012 | 1. FC Köln [Women] | - | SC 07 Bad Neuenahr II [Women] | 5:0 | ||||
| 2. Round | 09/09/2012 | 1. FC Köln [Women] | - | TSV Crailsheim [Women] | 1:1 | ||||
| 4. Round | 30/09/2012 | 1. FC Köln [Women] | - | Bayern München II [Women] | 3:2 | ||||
| 6. Round | 21/10/2012 | 1. FC Saarbrücken [Women] | - | 1. FC Köln [Women] | 0:1 | ||||
| 7. Round | 28/10/2012 | 1. FC Köln [Women] | - | SV Bardenbach [Women] | 12:1 |  |
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| 10. Round | 25/11/2012 | ETSV Würzburg [Women] | - | 1. FC Köln [Women] | 1:4 | ||||
| 11. Round | 02/12/2012 | 1. FC Köln [Women] | - | 1899 Hoffenheim [Women] | 1:1 | ||||
| 14. Round | 17/03/2013 | 1. FC Köln [Women] | - | 1. FFC Frankfurt II [Women] | 4:0 | ||||
| 15. Round | 24/03/2013 | Bayern München II [Women] | - | 1. FC Köln [Women] | 0:1 | |
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| 16. Round | 31/03/2013 | 1. FFC Recklinghausen [Women] | - | 1. FC Köln [Women] | 0:3 | ||||
| 19. Round | 28/04/2013 | 1. FC Köln [Women] | - | SC Sand [Women] | 0:1 | ||||
| 21. Round | 12/05/2013 | 1. FC Köln [Women] | - | ETSV Würzburg [Women] | 6:0 | |
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| 22. Round | 26/05/2013 | 1899 Hoffenheim [Women] | - | 1. FC Köln [Women] | 3:3 | |
Turkey