| 1. Round | 08/09/2013 | TuS Wörrstadt [Women] | - | 1. FC Köln [Women] | 0:8 | ||||
| 2. Round | 15/09/2013 | 1. FC Köln [Women] | - | SC 07 Bad Neuenahr [Women] | 3:0 |  |
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| 3. Round | 06/10/2013 | SV 67 Weinberg [Women] | - | 1. FC Köln [Women] | 2:3 | ||||
| 4. Round | 13/10/2013 | 1. FC Köln [Women] | - | 1. FFC 08 Niederkirchen [Women] | 3:0 | ||||
| 5. Round | 20/10/2013 | 1. FFC Frankfurt II [Women] | - | 1. FC Köln [Women] | 0:4 | ||||
| 6. Round | 27/10/2013 | 1. FC Köln [Women] | - | VfL Bochum [Women] | 2:1 | ||||
| 7. Round | 03/11/2013 | 1. FC Saarbrücken [Women] | - | 1. FC Köln [Women] | 1:2 | ||||
| 8. Round | 10/11/2013 | 1. FC Köln [Women] | - | TSV Crailsheim [Women] | 6:0 | ||||
| 9. Round | 24/11/2013 | ETSV Würzburg [Women] | - | 1. FC Köln [Women] | 1:2 | ||||
| 10. Round | 01/12/2013 | 1. FC Köln [Women] | - | SC Sand [Women] | 1:2 | ||||
| 11. Round | 15/02/2014 | Bayern München II [Women] | - | 1. FC Köln [Women] | 0:4 | ||||
| 12. Round | 23/02/2014 | 1. FC Köln [Women] | - | TuS Wörrstadt [Women] | 4:0 | |
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| 13. Round | 02/03/2014 | SC 13 Bad Neuenahr [Women] | - | 1. FC Köln [Women] | 1:3 | ||||
| 16. Round | 30/03/2014 | 1. FC Köln [Women] | - | 1. FFC Frankfurt II [Women] | 1:0 |
Germany