| 10. Round | 05/11/2006 | FC Schalke 04 | - | Bayern München | 2:2 | ||||
| 11. Round | 08/11/2006 | Bor. Mönchengladbach | - | FC Schalke 04 | 0:2 | ||||
| 12. Round | 11/11/2006 | FC Schalke 04 | - | 1. FSV Mainz 05 | 4:0 | ||||
| 13. Round | 18/11/2006 | Energie Cottbus | - | FC Schalke 04 | 2:4 |  |
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| 14. Round | 24/11/2006 | FC Schalke 04 | - | VfL Bochum | 2:1 | ||||
| 15. Round | 03/12/2006 | 1. FC Nürnberg | - | FC Schalke 04 | 0:0 | ||||
| 16. Round | 10/12/2006 | FC Schalke 04 | - | Borussia Dortmund | 3:1 | |
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| 17. Round | 16/12/2006 | Arminia Bielefeld | - | FC Schalke 04 | 0:1 | ||||
| 26. Round | 17/03/2007 | FC Schalke 04 | - | VfB Stuttgart | 1:0 | ||||
| 27. Round | 31/03/2007 | Bayern München | - | FC Schalke 04 | 2:0 | ||||
| 28. Round | 07/04/2007 | FC Schalke 04 | - | Bor. Mönchengladbach | 2:0 | ||||
| 29. Round | 14/04/2007 | 1. FSV Mainz 05 | - | FC Schalke 04 | 0:3 | ||||
| 30. Round | 21/04/2007 | FC Schalke 04 | - | Energie Cottbus | 2:0 | ||||
| 31. Round | 27/04/2007 | VfL Bochum | - | FC Schalke 04 | 2:1 | ||||
| 32. Round | 05/05/2007 | FC Schalke 04 | - | 1. FC Nürnberg | 1:0 | ||||
| 33. Round | 12/05/2007 | Borussia Dortmund | - | FC Schalke 04 | 2:0 |
Germany