| 2. Round | 15/08/2009 | Hamburger SV | - | Borussia Dortmund | 4:1 | ||||
| 3. Round | 22/08/2009 | Borussia Dortmund | - | VfB Stuttgart | 1:1 | ||||
| 5. Round | 12/09/2009 | Borussia Dortmund | - | Bayern München | 1:5 | ||||
| 7. Round | 26/09/2009 | Borussia Dortmund | - | FC Schalke 04 | 0:1 | ||||
| 10. Round | 23/10/2009 | Bayer Leverkusen | - | Borussia Dortmund | 1:1 | ||||
| 11. Round | 30/10/2009 | Borussia Dortmund | - | Hertha BSC | 2:0 |  |
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| 27. Round | 20/03/2010 | Borussia Dortmund | - | Bayer Leverkusen | 3:0 |  |
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| 30. Round | 10/04/2010 | 1. FSV Mainz 05 | - | Borussia Dortmund | 1:0 | ||||
| 33. Round | 01/05/2010 | Borussia Dortmund | - | VfL Wolfsburg | 1:1 | ||||
| 34. Round | 08/05/2010 | SC Freiburg | - | Borussia Dortmund | 3:1 |
Bulgaria