| 4. Round | 20/08/1966 | 1. FC Union Berlin | - | Dynamo Dresden | 2:2 | ||||
| 5. Round | 27/08/1966 | BSG Chemie Leipzig | - | 1. FC Union Berlin | 1:1 | ||||
| 6. Round | 24/09/1966 | 1. FC Union Berlin | - | 1. FC Lokomotive Leipzig | 1:0 | ||||
| 8. Round | 29/10/1966 | 1. FC Union Berlin | - | FC Karl-Marx-Stadt | 1:2 | ||||
| 12. Round | 19/11/1966 | 1. FC Union Berlin | - | BSG Motor Zwickau | 3:0 | ||||
| 13. Round | 26/11/1966 | BSG Lokomotive Stendal | - | 1. FC Union Berlin | 2:2 |  |
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| 24. Round | 07/05/1967 | 1. FC Union Berlin | - | BSG Wismut Aue | 0:3 | ||||
| 25. Round | 10/05/1967 | BSG Motor Zwickau | - | 1. FC Union Berlin | 5:0 | ||||
| 26. Round | 13/05/1967 | 1. FC Union Berlin | - | BSG Lokomotive Stendal | 3:1 |
Germany