| 1. Round | 20/08/1966 | Meidericher SV | - | Rot-Weiss Essen | 2:0 | ||||
| 2. Round | 27/08/1966 | Rot-Weiss Essen | - | FC Schalke 04 | 4:1 |  |
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| 3. Round | 03/09/1966 | 1. FC Kaiserslautern | - | Rot-Weiss Essen | 5:2 | ||||
| 4. Round | 10/09/1966 | Rot-Weiss Essen | - | Hamburger SV | 1:1 | ||||
| 5. Round | 17/09/1966 | Borussia Dortmund | - | Rot-Weiss Essen | 0:0 | ||||
| 12. Round | 05/11/1966 | 1. FC Nürnberg | - | Rot-Weiss Essen | 1:1 | ||||
| 13. Round | 12/11/1966 | Rot-Weiss Essen | - | Werder Bremen | 0:1 | ||||
| 18. Round | 07/01/1967 | Rot-Weiss Essen | - | MSV Duisburg | 0:1 |
Germany