| 1. Round | 11/08/2013 | VfL Theesen [Youth] | - | FC Schalke 04 [Youth] | 0:5 |  |
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| 5. Round | 15/09/2013 | FC Schalke 04 [Youth] | - | 1. FC Köln [Youth] | 0:2 | ||||
| 6. Round | 22/09/2013 | Rot-Weiß Oberhausen [Youth] | - | FC Schalke 04 [Youth] | 0:4 | ||||
| 8. Round | 19/10/2013 | FC Schalke 04 [Youth] | - | Fortuna Düsseldorf [Youth] | 5:2 | ||||
| 11. Round | 10/11/2013 | FC Schalke 04 [Youth] | - | Bonner SC [Youth] | 2:0 | ||||
| 12. Round | 23/11/2013 | MSV Duisburg [Youth] | - | FC Schalke 04 [Youth] | 3:3 | ||||
| 13. Round | 01/12/2013 | FC Schalke 04 [Youth] | - | Wuppertaler SV [Youth] | 3:0 | ||||
| 14. Round | 07/12/2013 | FC Schalke 04 [Youth] | - | VfL Theesen [Youth] | 10:0 | ||||
| 17. Round | 22/02/2014 | FC Schalke 04 [Youth] | - | Arminia Bielefeld [Youth] | 5:0 | ||||
| 19. Round | 19/03/2014 | FC Schalke 04 [Youth] | - | Rot-Weiß Oberhausen [Youth] | 4:1 | ||||
| 24. Round | 04/05/2014 | Bonner SC [Youth] | - | FC Schalke 04 [Youth] | 0:3 | ||||
| 25. Round | 11/05/2014 | FC Schalke 04 [Youth] | - | MSV Duisburg [Youth] | 3:0 | ||||
| 26. Round | 25/05/2014 | Wuppertaler SV [Youth] | - | FC Schalke 04 [Youth] | 0:3 |
Germany