| 1. Round | 06/08/2022 | 1. FC Union Berlin | - | Hertha BSC | 3:1 |  |
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| 5. Round | 03/09/2022 | 1. FC Union Berlin | - | Bayern München | 1:1 | ||||
| 9. Round | 09/10/2022 | VfB Stuttgart | - | 1. FC Union Berlin | 0:1 | |
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| 10. Round | 16/10/2022 | 1. FC Union Berlin | - | Borussia Dortmund | 2:0 | ||||
| 11. Round | 23/10/2022 | VfL Bochum | - | 1. FC Union Berlin | 2:1 | ||||
| 12. Round | 30/10/2022 | 1. FC Union Berlin | - | Bor. Mönchengladbach | 2:1 | ||||
| 16. Round | 21/01/2023 | 1. FC Union Berlin | - | 1899 Hoffenheim | 3:1 |  |
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| 17. Round | 25/01/2023 | Werder Bremen | - | 1. FC Union Berlin | 1:2 | ||||
| 19. Round | 04/02/2023 | 1. FC Union Berlin | - | 1. FSV Mainz 05 | 2:1 | ||||
| 22. Round | 26/02/2023 | Bayern München | - | 1. FC Union Berlin | 3:0 | ||||
| 25. Round | 19/03/2023 | 1. FC Union Berlin | - | Eintracht Frankfurt | 2:0 | ||||
| 26. Round | 01/04/2023 | 1. FC Union Berlin | - | VfB Stuttgart | 3:0 | ||||
| 27. Round | 08/04/2023 | Borussia Dortmund | - | 1. FC Union Berlin | 2:1 | ||||
| 31. Round | 06/05/2023 | FC Augsburg | - | 1. FC Union Berlin | 1:0 | ||||
| 32. Round | 13/05/2023 | 1. FC Union Berlin | - | SC Freiburg | 4:2 | ||||
| 33. Round | 20/05/2023 | 1899 Hoffenheim | - | 1. FC Union Berlin | 4:2 |
Germany
Ghana