| 3. Round | 18/08/2019 | Heracles Almelo | - | PSV Eindhoven | 0:2 | ||||
| 5. Round | 01/09/2019 | RKC Waalwijk | - | PSV Eindhoven | 1:3 | ||||
| 6. Round | 14/09/2019 | PSV Eindhoven | - | Vitesse | 5:0 | ||||
| 7. Round | 22/09/2019 | PSV Eindhoven | - | AFC Ajax | 1:1 | ||||
| 4. Round | 25/09/2019 | PSV Eindhoven | - | FC Groningen | 3:1 | ||||
| 8. Round | 29/09/2019 | PEC Zwolle | - | PSV Eindhoven | 0:4 | ||||
| 10. Round | 19/10/2019 | FC Utrecht | - | PSV Eindhoven | 3:0 |  |
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| 14. Round | 24/11/2019 | PSV Eindhoven | - | sc Heerenveen | 2:1 | ||||
| 18. Round | 21/12/2019 | PSV Eindhoven | - | PEC Zwolle | 4:1 |  |
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| 19. Round | 19/01/2020 | VVV-Venlo | - | PSV Eindhoven | 1:1 | ||||
| 20. Round | 26/01/2020 | PSV Eindhoven | - | FC Twente | 1:1 |  |
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| 21. Round | 02/02/2020 | AFC Ajax | - | PSV Eindhoven | 1:0 | ||||
| 22. Round | 08/02/2020 | PSV Eindhoven | - | Willem II | 3:0 | ||||
| 23. Round | 15/02/2020 | ADO Den Haag | - | PSV Eindhoven | 0:3 | ||||
| 24. Round | 23/02/2020 | Vitesse | - | PSV Eindhoven | 1:2 | ||||
| 25. Round | 01/03/2020 | PSV Eindhoven | - | Feyenoord | 1:1 | ||||
| 26. Round | 08/03/2020 | FC Groningen | - | PSV Eindhoven | 0:1 |
Netherlands