| 10. Round | 02/11/2019 | 1. FC Union Berlin | - | Hertha BSC | 1:0 | ||||
| 12. Round | 23/11/2019 | 1. FC Union Berlin | - | Bor. Mönchengladbach | 2:0 | ||||
| 14. Round | 08/12/2019 | 1. FC Union Berlin | - | 1. FC Köln | 2:0 | ||||
| 17. Round | 22/12/2019 | Fortuna Düsseldorf | - | 1. FC Union Berlin | 2:1 | ||||
| 18. Round | 18/01/2020 | RB Leipzig | - | 1. FC Union Berlin | 3:1 |  |
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| 19. Round | 25/01/2020 | 1. FC Union Berlin | - | FC Augsburg | 2:0 | ||||
| 20. Round | 01/02/2020 | Borussia Dortmund | - | 1. FC Union Berlin | 5:0 | ||||
| 21. Round | 08/02/2020 | Werder Bremen | - | 1. FC Union Berlin | 0:2 | ||||
| 23. Round | 24/02/2020 | Eintracht Frankfurt | - | 1. FC Union Berlin | 1:2 | |
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| 24. Round | 01/03/2020 | 1. FC Union Berlin | - | VfL Wolfsburg | 2:2 | ||||
| 26. Round | 17/05/2020 | 1. FC Union Berlin | - | Bayern München | 0:2 | ||||
| 27. Round | 22/05/2020 | Hertha BSC | - | 1. FC Union Berlin | 4:0 | ||||
| 28. Round | 27/05/2020 | 1. FC Union Berlin | - | 1. FSV Mainz 05 | 1:1 | ||||
| 29. Round | 31/05/2020 | Bor. Mönchengladbach | - | 1. FC Union Berlin | 4:1 |
Norway
USA