| 1. Round | 06/08/2022 | 1. FC Union Berlin | - | Hertha BSC | 3:1 | ||||
| 2. Round | 14/08/2022 | 1. FSV Mainz 05 | - | 1. FC Union Berlin | 0:0 | ||||
| 3. Round | 20/08/2022 | 1. FC Union Berlin | - | RB Leipzig | 2:1 | ||||
| 4. Round | 27/08/2022 | FC Schalke 04 | - | 1. FC Union Berlin | 1:6 | ||||
| 5. Round | 03/09/2022 | 1. FC Union Berlin | - | Bayern München | 1:1 | ||||
| 6. Round | 11/09/2022 | 1. FC Köln | - | 1. FC Union Berlin | 0:1 | ||||
| 9. Round | 09/10/2022 | VfB Stuttgart | - | 1. FC Union Berlin | 0:1 | ||||
| 10. Round | 16/10/2022 | 1. FC Union Berlin | - | Borussia Dortmund | 2:0 | ||||
| 11. Round | 23/10/2022 | VfL Bochum | - | 1. FC Union Berlin | 2:1 |  |
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| 12. Round | 30/10/2022 | 1. FC Union Berlin | - | Bor. Mönchengladbach | 2:1 | |
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| 13. Round | 06/11/2022 | Bayer Leverkusen | - | 1. FC Union Berlin | 5:0 | ||||
| 14. Round | 09/11/2022 | 1. FC Union Berlin | - | FC Augsburg | 2:2 | ||||
| 15. Round | 13/11/2022 | SC Freiburg | - | 1. FC Union Berlin | 4:1 |
Norway
USA