| 15. Round | 09/02/2014 | 1. FC Union Berlin [Youth B] | - | VfL Osnabrück [Youth B] | 2:0 | ||||
| 17. Round | 22/02/2014 | 1. FC Union Berlin [Youth B] | - | Dynamo Dresden [Youth B] | 1:1 |  |
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| 18. Round | 08/03/2014 | FC Carl Zeiss Jena [Youth B] | - | 1. FC Union Berlin [Youth B] | 4:0 | ||||
| 19. Round | 15/03/2014 | 1. FC Union Berlin [Youth B] | - | Eintracht Braunschweig [Youth B] | 0:0 | ||||
| 21. Round | 06/04/2014 | 1. FC Union Berlin [Youth B] | - | Hannover 96 [Youth B] | 2:2 | ||||
| 24. Round | 16/04/2014 | Energie Cottbus [Youth B] | - | 1. FC Union Berlin [Youth B] | 2:2 |  |
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| 22. Round | 04/05/2014 | FC St. Pauli [Youth B] | - | 1. FC Union Berlin [Youth B] | 2:1 | ||||
| 20. Round | 10/05/2014 | RB Leipzig [Youth B] | - | 1. FC Union Berlin [Youth B] | 3:1 | ||||
| 16. Round | 17/05/2014 | Holstein Kiel [Youth B] | - | 1. FC Union Berlin [Youth B] | 3:2 | ||||
| 23. Round | 24/05/2014 | 1. FC Union Berlin [Youth B] | - | Werder Bremen [Youth B] | 3:1 | ||||
| 25. Round | 01/06/2014 | Hertha BSC [Youth B] | - | 1. FC Union Berlin [Youth B] | 1:0 | |
Germany