| 3. Round | 15/02/2006 | FC Schalke 04 | - | Espanyol Barcelona | 2:1 | ||||
| 3. Round | 23/02/2006 | Espanyol Barcelona | - | FC Schalke 04 | 0:3 |  |
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| Quarter-finals | 30/03/2006 | Levski Sofia | - | FC Schalke 04 | 1:3 | ||||
| Quarter-finals | 06/04/2006 | FC Schalke 04 | - | Levski Sofia | 1:1 | ||||
| Semi-finals | 20/04/2006 | FC Schalke 04 | - | Sevilla FC | 0:0 | ||||
| Semi-finals | 27/04/2006 | Sevilla FC | - | FC Schalke 04 | 1:0 aet |  |
Brazil
